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危险类别码	R36/37/38
安全说明书	S26

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Sigma-Aldrich	浏览或下载
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Nickel-catalyzed borylation of halides and pseudohalides with tetrahydroxydiboron [B2 (OH) 4].Molander G A, et al. The Journal of Organic Chemistry, 78(13), 6427-6439 (2013) Palladium pincer complex catalyzed substitution of vinyl cyclopropanes, vinyl aziridines, and allyl acetates with tetrahydroxydiboron. An efficient route to functionalized allylboronic acids and potassium trifluoro (allyl) borates.Sebelius S et al. Journal of the American Chemical Society, 127(30), 10478-10479 (2005) Palladium-catalyzed, direct boronic acid synthesis from aryl chlorides: a simplified route to diverse boronate ester derivatives.Molander G A, et al. Journal of the American Chemical Society, 132(50), 17701-17703 (2010) Rapid and Selective in situ Reduction of Pyridine-N-oxides with Tetrahydroxydiboron.Londregan A T Synlett, 24(20), 2695-2700 (2013) Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/ Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid.Molander GA, et al. The Journal of Organic Chemistry, 77, 8678-8688 (2012) Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid.Molander GA, et al. Journal of the American Chemical Society, 134, 11667-11673 (2012) Tetrahydroxydiboron-Mediated Palladium-Catalyzed Transfer Hydrogenation and Deuteriation of Alkenes and Alkynes Using Water as the Stoichiometric H or D Atom Donor.Cummings S P, et al. Journal of the American Chemical Society, 138(19), 6107-6110 (2016) Development and Scale-up of an Efficient Miyaura Borylation Process Using Tetrahydroxydiboron.Gurung S R, et al. Organic Process Research & Development, 21(1), 65-74 (2016)

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