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Tolylene-2,4-diisocyanate | CAS:584-84-9
Tolylene-2,4-diisocyanate
  • 名称:甲苯-2,4-二异氰酸酯; 2,4-二异酸甲苯酯 | Tolylene-2,4-diisocyanate
  • CAS号:584-84-9
  • 别名:4-Methyl-1,3-phenylene diisocyanate; 2,4-Diisocyanatotoluene; TDI
  • 分子式:C9H6N2O2
  • 分子量:174.16
  • EINESC号:209-544-5

产品描述

物理化学性质

熔点 12.5-13.5 ºC
水溶性 起反应
沸点 115-120 ºC (10 mmHg)
闪点 127 ºC
密度 1.225
折射率 1.567-1.569

安全数据

危险品标志 T+
危险类别码 R26;R36/37/38;R40;R42/43;R52/53
安全说明书 S23;S36/37;S45;S61

SDS

来源 SDS样本
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Asymmetric synthesis of (-)-aurantioclavine via palladium-catalyzed intramolecular allylic amination.Satoshi Suetsugu et al.Organic letters, 16(3), 996-999 (2014-01-28) Palladium-catalyzed β arylation of carboxylic esters.Alice Renaudat et al.Angewandte Chemie (International ed. in English), 49(40), 7261-7265 (2010-08-21) European Journal of Inorganic Chemistry, 6, 1262-1269 (2004) The elusive structure of Pd2(dba)3. Examination by isotopic labeling, NMR spectroscopy, and X-ray diffraction analysis: synthesis and characterization of Pd2(dba-Z)3 complexes.Anant R Kapdi et al.Journal of the American Chemical Society, 135(22), 8388-8399 (2013-05-25) Littke, A. F.; Dai, C.; Fu, G.C. Journal of the American Chemical Society, 122, 4020-4020 (2000) Kawatsura, M.; Hartwig, J. F. Journal of the American Chemical Society, 121, 1473-1473 (1999) Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.Xiaoqiang Shen et al.Journal of the American Chemical Society, 132(40), 14076-14078 (2010-09-23) Palladium-catalyzed asymmetric synthesis of allylic fluorides.Matthew H Katcher et al.Journal of the American Chemical Society, 132(49), 17402-17404 (2010-11-23) Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.Michael J Ardolino et al.Tetrahedron, 71(37), 6409-6413 (2015-08-19) Tris DBA Ameliorates Accelerated and Severe Lupus Nephritis in Mice by Activating Regulatory T Cells and Autophagy and Inhibiting the NLRP3 Inflammasome.Chung-Yao Wu et al.Journal of immunology (Baltimore, Md. : 1950), 204(6), 1448-1461 (2020-02-16) Pd(0)-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates.Martin Arthuis et al.Chemical communications (Cambridge, England), 46(41), 7810-7812 (2010-09-21) Efficient syntheses of [¹¹C]zidovudine and its analogs by convenient one-pot palladium(0)-copper(I) co-mediated rapid C-[¹¹C]methylation.Zhouen Zhang et al.Journal of labelled compounds & radiopharmaceuticals, 57(8), 540-549 (2014-07-06) Crystal and molecular structure of tris (dibenzylideneacetone) dipalladium (0).Pierpont CG and Mazza MC Inorganic Chemistry, 13(8), 1891-1895 (1974) Wolfe, J. P.; Wagaw, S.; Buchwald, S. L. Journal of the American Chemical Society, 118, 7215-7215 (1996) Carborane-derived local anesthetics are isomer dependent.George R Kracke et al.ChemMedChem, 10(1), 62-67 (2014-11-26) Asymmetric synthesis of new beta,beta-difluorinated cyclic quaternary alpha-amino acid derivatives.Santos Fustero et al.Organic letters, 8(18), 4129-4132 (2006-08-25) Tetrahedron Letters, 33, 4859-4859 (1992) Chemistry (Weinheim An Der Bergstrasse, Germany), 12, 5657-5657 (2006)
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