
2-Methylphenyl isothiocyanate | CAS:614-69-7
2-Methylphenyl isothiocyanate
- 名称:邻甲苯异硫氰酸酯; 异硫氰酸邻甲苯酯 | 2-Methylphenyl isothiocyanate
- CAS号:614-69-7
- 别名:o-Tolyl isothiocyanate
- 分子式:C8H7NS
- 分子量:149.21
- EINESC号:210-390-6
产品描述
物理化学性质
水溶性 | may 分解ose |
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沸点 | 239 ºC |
闪点 | 107 ºC |
密度 | 1.115 |
折射率 | 1.6351-1.6371 |
安全数据
危险品标志 | Xn |
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危险类别码 | R20/21/22;R42/43 |
安全说明书 | S26;S36/37/39;S45 |
产品合成路线
名称 | CAS号 |
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同行评议文献
An effective method for studying intermolecular interactions in binary liquids with hydrogen bonds; FTIR spectra and ab initio calculations in the N-methylformamide-methanol system.Ewa Kamieńska-Piotrowicz et al.The journal of physical chemistry. B, 114(17), 5810-5818 (2010-04-13)
Integration of clinical chemistry, expression, and metabolite data leads to better toxicological class separation.Jeppe S Spicker et al.Toxicological sciences : an official journal of the Society of Toxicology, 102(2), 444-454 (2008-01-08)
CH stretching vibration of N-methylformamide as a sensitive probe of its complexation: infrared matrix isolation and computational study.M Sałdyka et al.Physical chemistry chemical physics : PCCP, 13(31), 13992-14002 (2011-07-12)
N-Methylcarbamoyl-lysine adduct in globin: a new metabolic product and potential biomarker of N, N-dimethylformamide in humans.J Mráz et al.Toxicology letters, 162(2-3), 211-218 (2005-11-18)
N-methylformamide, a hyperplectic model for peptides in thin film infrared spectroscopy on planar AgX.Edward M Kosower et al.The journal of physical chemistry. B, 113(16), 5622-5632 (2009-03-31)
How water links to cis and trans peptidic groups: the rotational spectrum of N-methylformamide-water.Walther Caminati et al.Physical chemistry chemical physics : PCCP, 12(35), 10230-10234 (2010-07-27)
Conductivity dynamics and static dielectric permittivity of highly conducting molecular liquids studied with impedance spectroscopy. Formamides.Jolanta Swiergiel et al.The journal of physical chemistry. B, 113(43), 14225-14228 (2009-10-07)
Quasiplanarity of the peptide bond.Jakub Chalupský et al.The journal of physical chemistry. A, 112(4), 693-699 (2008-01-08)
Liquid-phase synthesis of a Li3PS4 solid electrolyte using N-methylformamide for all-solid-state lithium batteries.Teragawa S, et al. Journal of Material Chemistry A, 2(14), 5095-5099 (2014)
Amidic and acetonic cryoprotectants improve cryopreservation of volvocine green algae.A Nakazawa et al.Cryo letters, 33(3), 202-213 (2012-07-25)
N-methylformamide as a separation medium in capillary electrophoresis. Jansson M and Roeraade J. Chromatographia, 40(3-4), 163-169 (1995)
Identification of potential genomic biomarkers of hepatotoxicity caused by reactive metabolites of N-methylformamide: Application of stable isotope labeled compounds in toxicogenomic studies.Abdul Mutlib et al.Chemical research in toxicology, 19(10), 1270-1283 (2006-10-17)
Cryoprotectant toxicity neutralization.Gregory M Fahy Cryobiology, 60(3 Suppl), S45-S53 (2009-06-09)
Theoretical exploration of the cooperative effect in NMF-NMF-amino acid residue hydrogen bonding system.Xichen Li et al.Physical chemistry chemical physics : PCCP, 10(36), 5607-5615 (2008-10-29)
[High performance liquid chromatography for determination of N-acetyl-S-(N-methylformamide) cysteine in human urine derivative oscillopolarography for determination of urine arsenic].Jun He et al.Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 27(2), 103-104 (2009-04-09)
Mitochondrial DNA alterations in blood of the humans exposed to N,N-dimethylformamide.Dar-Bin Shieh et al.Chemico-biological interactions, 165(3), 211-219 (2007-01-27)
[N-methylformamide in urine].Hideki Igisu et al.Nihon rinsho. Japanese journal of clinical medicine, 62 Suppl 12, 488-490 (2005-01-22)
Photochemistry of N-methylformamide: matrix isolation and nonadiabatic dynamics.Rachel Crespo-Otero et al.Chemphyschem : a European journal of chemical physics and physical chemistry, 14(4), 827-836 (2012-10-04)
A hybrid neutron diffraction and computer simulation study on the solvation of N-methylformamide in dimethylsulfoxide.João M M Cordeiro et al.The Journal of chemical physics, 138(4), 044502-044502 (2013-02-08)
Combining novel strategy with kinetic approach in the determination of respective respiration and skin exposure to N,N-dimethylformamide vapor.Shih-Min Wang et al.The Science of the total environment, 388(1-3), 398-404 (2007-09-15)
N-methylformamide: cytotoxic, radiosensitizer, or chemosensitizer.K Clagett-Carr et al.Journal of clinical oncology : official journal of the American Society of Clinical Oncology, 6(5), 906-918 (1988-05-01)
Glycerol, methyl-formamide and dimethyl-formamide in canine semen cryopreservation.D O Futino et al.Reproduction in domestic animals = Zuchthygiene, 45(2), 214-220 (2008-11-21)
Use of N-methylformamide as a solvent in indium-promoted Barbier reactions en route to enediyne and epoxy diyne formation: comparison of rate and stereoselectivity in C-C bond-forming reactions with water.Kwame Frimpong et al.The Journal of organic chemistry, 74(16), 5861-5870 (2009-07-29)
Interlayer condensation of protonated layered silicate magadiite through refluxing in N-methylformamide.Asakura Y, et al. Bulletin of the Chemical Society of Japan, 88(9), 1241-1249 (2015)
Femtosecond dynamics of hydrogen-bonding solvents. Formamide and N-methylformamide in acetonitrile, DMF, and water. Chang JY and Castner Jr EW. J. Chem. Phys. , 99(1), 113-125 (1993)
Effect of pre-freeze semen quality, extender and cryoprotectant on the post-thaw quality of Asian elephant (Elephas maximus indicus) semen.P Imrat et al.Cryobiology, 66(1), 52-59 (2012-11-22)
Preparation of Li2S-P2S5 solid electrolyte from N-methylformamide solution and application for all-solid-state lithium battery.Teragawa S, et al. Journal of Power Sources, 248, 939-942 (2014)
Elementary peptide motifs in the gas phase: FTIR aggregation study of formamide, acetamide, N-methylformamide, and N-methylacetamide.Merwe Albrecht et al.The journal of physical chemistry. A, 112(33), 7530-7542 (2008-07-31)
Comparative transport efficiencies of urea analogues through urea transporter UT-B.Dan Zhao et al.Biochimica et biophysica acta, 1768(7), 1815-1821 (2007-05-18)
Pd(II)-catalyzed ortho trifluoromethylation of arenes and insights into the coordination mode of acidic amide directing groups.Xing-Guo Zhang et al.Journal of the American Chemical Society, 134(29), 11948-11951 (2012-07-12)
Aerobic biodegradation of N-nitrosodimethylamine by the propanotroph Rhodococcus ruber ENV425.Diane Fournier et al.Applied and environmental microbiology, 75(15), 5088-5093 (2009-06-23)
N-methylformamide: antitumour activity and metabolism in mice.A Gescher et al.British journal of cancer, 45(6), 843-850 (1982-06-01)
Surface-enhanced resonance Raman scattering nanostars for high-precision cancer imaging.Stefan Harmsen et al.Science translational medicine, 7(271), 271ra7-271ra7 (2015-01-23)
Electric field effects on one-bond indirect spin-spin coupling constants and possible biomolecular perspectives.Aleksandr B Sahakyan et al.The journal of physical chemistry. A, 112(16), 3576-3586 (2008-03-28)
Separation of oligonucleotides in N-methyl-formamide-based polymer matrices by capillary electrophoresis.Johan Sjödahl et al.Journal of separation science, 30(1), 104-109 (2007-02-23)
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