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Hexaethylene glycol | CAS:2615-15-8
Hexaethylene glycol
  • 名称:六甘醇; 六聚乙二醇; 聚乙二醇-6; PEG-6 | Hexaethylene glycol
  • CAS号:2615-15-8
  • 别名:3,6,9,12,15-Pentaoxaheptadecane-1,17-diol
  • 分子式:C12H26O7
  • 分子量:282.33
  • EINESC号:220-045-1

产品描述

物理化学性质

熔点 5-7 ºC
沸点 217 ºC (4 mmHg)
闪点 110 ºC
密度 1.127
折射率 1.465

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Synthesis of trifluoromethyl ketones by palladium-catalyzed cross-coupling reaction of phenyl trifluoroacetate with organoboron compoundsKakino R, et al. Bulletin of the Chemical Society of Japan, 74(2), 371-376 (2001) Electron-transfer self-exchange kinetics of trimethylphosphine horse-heart myoglobin.C Brunel et al.Biochimica et biophysica acta, 1101(1), 73-78 (1992-07-06) 31P chemical shifts as structural probes for heme environments. 31P-NMR study of the binding of trimethyl phosphine to various hemoglobins and myoglobins.A Bondon et al.Biochimica et biophysica acta, 872(1-2), 163-166 (1986-07-25) Preparation of (cyanomethylene)trimethylphosphorane as a new Mitsunobu-type reagent.Izumi Sakamoto et al.Chemical & pharmaceutical bulletin, 51(4), 474-476 (2003-04-04) Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of certain alcohols and aminesMunshi P, et al. Journal of the American Chemical Society, 124(27), 7963-7971 (2002) Synthesis and evaluation of technetium-99m monocationic mixed ligand complexes of phenyl substituted/condensed tetradentate Schiff's bases and trimethylphosphine.N C Goomer et al.International journal of radiation applications and instrumentation. Part B, Nuclear medicine and biology, 19(6), 679-684 (1992-08-01) 31P-NMR investigation of trimethylphosphine binding to [alpha Fe(II), beta Mn(II)] hybrid hemoglobin. A model for partially liganded species.A Bondon et al.Biophysical chemistry, 37(1-3), 407-411 (1990-08-31) Rohloff, J. C.; Kent, K. M. et al. The Journal of Organic Chemistry, 63, 4545-4545 (1998) Phosphines as a new structural probe of hemoglobin. 1H-NMR evidence for perturbations in the beta heme pocket induced by a thiol reagent.A Bondon et al.Biochimica et biophysica acta, 914(3), 289-293 (1987-08-21) One-pot conversion of azides to Boc-protected amines with trimethylphosphine and Boc-ONAriza X, et al. Tetrahedron Letters, 39(49), 9101-9102 (1998) Trimethylphosphine binding to horse-heart and sperm-whale myoglobins. Kinetics, proton magnetic resonance assignment and nuclear Overhauser effect investigation of the heme pocket.C Brunel et al.European journal of biochemistry, 214(2), 405-414 (1993-06-01) Phosphine-initiated general base catalysis: facile access to benzannulated 1,3-diheteroatom five-membered rings via double-Michael reactions of allenes.Judy Szeto et al.Organic letters, 13(20), 5420-5423 (2011-09-22) Mechanistic study of the synthesis of CdSe nanocrystals: release of selenium.Raúl García-Rodríguez et al.Journal of the American Chemical Society, 134(3), 1400-1403 (2012-01-10) C- H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their ReactivitiesCamadanli S, et al. Organometallics, 28(7), 2300-2310 (2009) Orthoacylimines: a new class of chiral auxiliaries for nucleophilic addition of organolithium reagents to imines.Alessandro A Boezio et al.The Journal of organic chemistry, 68(8), 3241-3245 (2003-04-12) Aza-Wittig reaction of N-phosphorylalkyl phosphazenes with carbonyl compounds and phenylisocyanate. Synthesis of 4-amino-3-phosphoryl-2-azadienes and pyrazine-phosphonatesPalacios F, et al. Tetrahedron, 59(15), 2617-2623 (2003) Proton hyperfine resonance assignments in trimethylphosphine ligated ferrimyoglobin using saturation transfer spectroscopy.G Simonneaux et al.Biochimica et biophysica acta, 1038(2), 199-203 (1990-04-19) The synthetic-technical development of oseltamivir phosphate [TM="Tamiflu"]: A race against timeAbrecht S, et al. Chimia, 61(3), 93-99 (2007) Conversion of ketoximes to ketones with trimethylphosphine and 2, 2′-dipyridyl diselenideMartin M, et al. Tetrahedron Letters, 45(29), 5559-5561 (2004) Ariza, X.; Urpi, F.; Vilarrasa, J. Tetrahedron Letters, 40, 7515-7515 (1999) Molybdenum complex with bulky chelates as a functional model for molybdenum oxidases.Jana Leppin et al.Inorganic chemistry, 53(23), 12416-12427 (2014-11-14) Soft diphosphine and diarsine complexes of niobium(V) and tantalum(V) fluorides: synthesis, properties, structures and comparisons with the corresponding chlorides.William Levason et al.Dalton transactions (Cambridge, England : 2003), 43(25), 9557-9566 (2014-05-16) Reactivity of an All-Ferrous Iron-Nitrogen Heterocubane under Reductive and Oxidative Conditions.Crispin Lichtenberg et al.Chemistry (Weinheim an der Bergstrasse, Germany), 21(44), 15797-15805 (2015-09-17) Change of surface structure upon foam film formation.Christiaan Ridings et al.Chemphyschem : a European journal of chemical physics and physical chemistry, 16(4), 733-738 (2015-02-14) Tsunoda, T, et al. Tetrahedron Letters, 34, 1639-1639 (1993) Synthetic studies toward FR182877. Remarkable solvent effect in the vinylogous morita-baylis-hillman cyclization.Joey L Methot et al.Organic letters, 5(22), 4223-4226 (2003-10-24)
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