Phenylmagnesium chloride | CAS:100-59-4
            
            Phenylmagnesium chloride
            - 名称:苯基氯化镁 | Phenylmagnesium chloride
 - CAS号:100-59-4
 - 别名:
 - 分子式:C6H5ClMg
 - 分子量:136.86
 - EINESC号:202-868-8
 
产品描述
物理化学性质
| 熔点 | 89-90 ºC* | 
|---|---|
| 沸点 | 230 ºC (8 Torr)* | 
安全数据
| 没有数据 | 没有数据 | 
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SDS
| 来源 | SDS样本 | 
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| 没有数据 | 没有数据 | 
产品合成路线
                | 名称 | CAS号 | 
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                                        Novel anti-Prelog stereospecific carbonyl reductases from Candida parapsilosis for asymmetric reduction of prochiral ketones.Yao Nie et al.Organic & biomolecular chemistry, 9(11), 4070-4078 (2011-04-21)
                                        A novel approach based on solid phase microextraction gas chromatography and mass spectrometry to the determination of highly reactive organic compounds in cells cultures: styrene oxide.Diana Poli et al.Chemical research in toxicology, 17(1), 104-109 (2004-01-20)
                                        A novel NADH-dependent carbonyl reductase with unusual stereoselectivity for (R)-specific reduction from an (S)-1-phenyl-1,2-ethanediol-producing micro-organism: purification and characterization.Y Nie et al.Letters in applied microbiology, 44(5), 555-562 (2007-04-25)
                                        Metabolism of styrene oxide to styrene glycol in enriched mouse clara-cell preparations.G P Carlson Journal of toxicology and environmental health. Part A, 61(8), 709-717 (2001-01-02)
                                        Colorimetric assays for quantitative analysis and screening of epoxide hydrolase activity.F Cedrone et al.Biotechnology letters, 27(23-24), 1921-1927 (2005-12-06)
                                        Sortase A-mediated crosslinked short-chain dehydrogenases/reductases as novel biocatalysts with improved thermostability and catalytic efficiency.Kunpeng Li et al.Scientific reports, 7(1), 3081-3081 (2017-06-10)
                                        A new strategy to improve the efficiency and sustainability of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol under non-growing conditions: increase of NADPH availability.Yao Nie et al.Journal of microbiology and biotechnology, 19(1), 65-71 (2009-02-05)
                                        Highly enantioselective reduction of 2-hydroxy-1-phenylethanone to enantiopure (R)-phenyl-1,2-ethanediol using Saccharomyces cerevisiae of remarkable reaction stability.Qingsen Hu et al.Bioresource technology, 101(22), 8502-8508 (2010-07-16)
                                        Kinetic resolution of 1,2-diols using immobilized Burkholderia cepacia lipase: A combined experimental and molecular dynamics investigation.Ashwini C Mathpati et al.Journal of biotechnology, 262, 1-10 (2017-09-30)
                                        [Hydrophobic membrane chromatography for fast purification of biological macromolecules].L Yang et al.Se pu = Chinese journal of chromatography, 17(4), 335-338 (2003-01-30)
                                        Protein engineering of epoxide hydrolase from Agrobacterium radiobacter AD1 for enhanced activity and enantioselective production of (R)-1-phenylethane-1,2-diol.Lingyun Rui et al.Applied and environmental microbiology, 71(7), 3995-4003 (2005-07-08)
                                        Enzymatic resolution of racemic phenyloxirane by a novel epoxide hydrolase from Aspergillus niger SQ-6 and its fed-batch fermentation.Yanbin Liu et al.Journal of industrial microbiology & biotechnology, 33(4), 274-282 (2005-12-02)
                                        [Gene cloning and expression of a novel (S)-specific carbonyl reductase].Yawei Geng et al.Wei sheng wu xue bao = Acta microbiologica Sinica, 50(1), 60-66 (2010-03-30)
                                        An approach based on liquid chromatography/electrospray ionization-mass spectrometry to detect diol metabolites as biomarkers of exposure to styrene and 1,3-butadiene.Shuijie Shen et al.Analytical biochemistry, 386(2), 186-193 (2008-12-30)
                                        DNA single strand breaks induced by low levels of occupational exposure to styrene: the gap between standards and reality.Magdy Y Shamy et al.Journal of environmental pathology, toxicology and oncology : official organ of the International Society for Environmental Toxicology and Cancer, 21(1), 57-61 (2002-04-06)
                                        Block copolymers of ethylene oxide and phenyl glycidyl ether: micellization, gelation, and drug solubilization.Pablo Taboada et al.Langmuir : the ACS journal of surfaces and colloids, 21(12), 5263-5271 (2005-06-01)
                                        Enhancement of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol to its (S)-enantiomer by a highly productive "two-in-one" resin-based in situ product removal strategy.Qingsen Hu et al.Bioresource technology, 101(21), 8461-8463 (2010-06-25)
                                        Efficient one-step production of (S)-1-phenyl-1,2-ethanediol from (R)-enantiomer plus NAD(+)-NADPH in-situ regeneration using engineered Escherichia coli.Rongzhen Zhang et al.Microbial cell factories, 11, 167-167 (2013-01-01)
                                        Biosynthesis of (R)-phenyl-1,2-ethanediol from racemic styrene oxide by using bacterial and marine fish epoxide hydrolases.Hee Sook Kim et al.Biotechnology letters, 30(1), 127-133 (2007-08-01)
                                        Improved production of (R)-1-phenyl-1,2-ethanediol by a codon-optimized R-specific carbonyl reductase from Candida parapsilosis in Escherichia coli.Rongzhen Zhang et al.Applied biochemistry and biotechnology, 160(3), 868-878 (2009-02-12)
                                        Simultaneous determination of phenylglyoxylic acid, mandelic acid, styrene glycol and hippuric acid in primary culture of rat hepatocytes incubate by high-performance liquid chromatography.Jin-Zhao Wang et al.Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)
                                        A spectrophotometric assay for measuring and detecting an epoxide hydrolase activity.Cesar Mateo et al.Analytical biochemistry, 314(1), 135-141 (2003-03-14)
                                        Enantioconvergent production of (R)-1-phenyl-1,2-ethanediol from styrene oxide by combining the Solanum tuberosum and an evolved Agrobacterium radiobacter AD1 epoxide hydrolases.Li Cao et al.Biotechnology and bioengineering, 94(3), 522-529 (2006-02-25)
                                        Kinetic resolution of racemic styrene oxide at a high concentration by recombinant Aspergillus usamii epoxide hydrolase in an n-hexanol/buffer biphasic system.Die Hu et al.Journal of biotechnology, 236, 152-158 (2016-08-23)
                                        Structure activity relationship of human microsomal epoxide hydrolase inhibition by amide and acid analogues of valproic acid.O Spiegelstein et al.Pharmaceutical research, 17(2), 216-221 (2000-04-06)
                                        [Construction of an enzyme-coupled system consisting of (R)- and (S)-specific carbonyl reductases for one-step preparation of (S)-1-phenyl-1,2-ethanediol].Rongzhen Zhang et al.Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)
                                        Essential oils and fatty acids composition of Tunisian and Indian cumin (Cuminum cyminum L.) seeds: a comparative study.Iness Bettaieb et al.Journal of the science of food and agriculture, 91(11), 2100-2107 (2011-06-18)
                                        Carbonyl reductase SCRII from Candida parapsilosis catalyzes anti-Prelog reaction to (S)-1-phenyl-1,2-ethanediol with absolute stereochemical selectivity.Rongzhen Zhang et al.Bioresource technology, 102(2), 483-489 (2010-09-14)
                                    
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            Products protected by valid patents are not offered for sale in countries where the sale of such products constitutes a patent infringement and its liability is at buyer's risk.
Products currently covered by valid US Patents are offered for R&D use in accordance with 35 USC 271 +A13(1).
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